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A Chemical Reaction that is Powered by Light 

Tommy Technetium
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In the presence of light, thionin dye reacts with iron (II) ions to form a colorless dye. What color of light causes this reaction to occur? Learn some simple tests you can do to figure this out!

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26 сен 2024

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Комментарии : 48   
@anomatoor
@anomatoor 2 года назад
Thanks for explaining this reaction in more detail than you did in the shorts video. I think this is a really cool reaction!
@FredericoMirandaBrandaoAlves
@FredericoMirandaBrandaoAlves 18 дней назад
Thanks for the demonstration! This could have uses for chemical reactions where the presence of Iron (III) ions is useful: they could work as electron acceptor and be reduced to iron (II), thus a catalytic cycle is formed.
@johannaverplank4858
@johannaverplank4858 2 года назад
Are there any practical applications for these color changing chemicals? Thanks for the video!
@TommyTechnetium
@TommyTechnetium 2 года назад
Thionin is used as a stain in various biological systems
@dinohunter7176
@dinohunter7176 2 года назад
I would fill windows with it. When night comes instead of reddish sunset, I would see purple-ish or just blue.
@luna010
@luna010 2 года назад
Well I’m currently looking into using them for photography. Looking for compounds that react with visible light in a reversible manner, and I stumbled upon this.
@petevenuti7355
@petevenuti7355 Год назад
@@luna010 what other things have you found so far? Do You understand how photosensitizers work in color film and the complicated matters of electron transport , quenching of energy and such that? Cuz I sure don't!
@spikarooni6391
@spikarooni6391 2 года назад
Fascinating demo
@TommyTechnetium
@TommyTechnetium 2 года назад
Thank you 😊
@freehat2722
@freehat2722 Год назад
Well made.
@experimental_chemistry
@experimental_chemistry 2 года назад
Wow! What a cool channel! Just discovered it... Does anybody know where thionin can be bought by private persons in the EU?
@zachreyhelmberger894
@zachreyhelmberger894 Год назад
Really liked the effect of half the beaker being illuminated! I suppose the liquid has to be very still before turning the light on..
@TommyTechnetium
@TommyTechnetium Год назад
Indeed
@AdricM
@AdricM 2 года назад
very cool.
@aneutralopinion1712
@aneutralopinion1712 2 года назад
Is this what is used for biology classes to dye cells? I love this btw:)
@TommyTechnetium
@TommyTechnetium 2 года назад
Thank you, and yes, thionin is often used as a biological stain
@TommyTechnetium
@TommyTechnetium 2 года назад
It is indeed a very interesting reaction!
@aneutralopinion1712
@aneutralopinion1712 2 года назад
That's so cool!
@petevenuti7355
@petevenuti7355 Год назад
Does it go by other names?
@henryrroland
@henryrroland 2 года назад
I have a question... Is the amount of light shifting the equilibrium constant? If it is happening, what's the mechanism foton-iron-dye?
@kylelovell121
@kylelovell121 2 года назад
i would also like to know the mechanism behind this. please make a follow up video
@TommyTechnetium
@TommyTechnetium 2 года назад
You can learn a bit more about this reaction here www.chemedx.org/blog/exploring-“two-faced”-thionin-reaction
@CDev15
@CDev15 2 года назад
Conjugated systems!
@TommyTechnetium
@TommyTechnetium 2 года назад
...for the win!
@petevenuti7355
@petevenuti7355 Год назад
Besides a bunch of pi-pi bonds and resonate structures, what makes this molecule a special 'system' that allows it to participate in photoredox reactions like this?
@Thelearninglouge
@Thelearninglouge Год назад
@@TommyTechnetiumu are so funny😂
@the_clover_star
@the_clover_star 2 года назад
Cool!!
@1495978707
@1495978707 2 года назад
This is *thionine*, thionin is a protein
@kylelovell121
@kylelovell121 2 года назад
i would also like to know the mechanism behind this. please make a follow up video
@TommyTechnetium
@TommyTechnetium 2 года назад
Thank you for this suggestion. You can learn a bit more about the mechanism and other aspects of this reaction here www.chemedx.org/blog/exploring-“two-faced”-thionin-reaction
@user255
@user255 Год назад
Nice demonstration. Judging from the structure thionin is probably carcinogen..?
@JuiicyDrew
@JuiicyDrew 2 года назад
Do this over a stencil please!
@TommyTechnetium
@TommyTechnetium 2 года назад
Great idea!
@petevenuti7355
@petevenuti7355 Год назад
Let's see a QR code in gelatin, with a 😜 in the middle or a 👍. Do you have a logo? Tag. Symbol? Trademark? With the right yellow blocking filter a sodium lamp under & maybe strontium lamp from the top ... Yeah.... maybe
@petevenuti7355
@petevenuti7355 Год назад
I assume this also works with other multivalent ions besides iron?
@TommyTechnetium
@TommyTechnetium Год назад
Good question....
@daymarportt4880
@daymarportt4880 9 месяцев назад
Is the solution toxic and i notice the gloves so im àssuming it cant be handle directly , i was thinking that would make a interesting toys for kids but i strongly believe that would be to dangerous
@TommyTechnetium
@TommyTechnetium 9 месяцев назад
Probably right 😞
@petevenuti7355
@petevenuti7355 Год назад
If you put electrodes between the transparent part and the colored part you get a potential? Can you add a potential to get the same effect without light? What are the counter ions and PH and what effect to do they have?
@TommyTechnetium
@TommyTechnetium Год назад
Great idea regarding measuring potential difference between the two sides of the solution!! If you'd like to learn more, check out the following link (and references contained therein) www.chemedx.org/blog/exploring-“two-faced”-thionin-reaction
@petevenuti7355
@petevenuti7355 Год назад
@@TommyTechnetium yes that totally looks like a battery reaction!
@petevenuti7355
@petevenuti7355 Год назад
Are you going to try it? Or get your class to play with the idea? What about Methylene blue? It's very similar, just not sure there's enough potential at the peek of its absorption wavelength to do the same thing. It's cheaper and easier for me to get. How would one demethylate Methylene blue?
@TommyTechnetium
@TommyTechnetium Год назад
@@petevenuti7355 I hope to try it at some point. Unfortunately I'm working on other experiments right now so it will be awhile
@petevenuti7355
@petevenuti7355 Год назад
I never got thionine to try myself, but apparently the answers are YES! It's called the photogalvantic effect. Studied by E. Rabinowitch at MIT till 1940. Not much work has been done on on this or similar chemistry since, that's like no progress in 80 years!!!! Isn't that crazy!
@Berghiker
@Berghiker 2 года назад
In your other experiment with methylene blue, what wavelength is your UV laser working at? 395nm or 365nm? or is it a blue/purple laser?
@specialistvlad
@specialistvlad 2 года назад
Sound sucks sorry
@wolfisr
@wolfisr 2 года назад
Thats a fantastic demo! 'e' is missing in Fe at the products of the reaction. It's not fluorine but iron!
@TommyTechnetium
@TommyTechnetium 2 года назад
Thanks for the correction
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