In this case, i would say the best characters are the ones that make the best team? That would be full gear herrscher trio. So much coverage and a lot of good scores on many diferent metas
Herrscher Trio. They cover almost all the bosses in the game. And the best character for investment is Herrscher of Truth full set, because she works almost in any elemental teams as support. For physical, grab for Herrscher of Rebirth (impair and crit buff) this coming patch and Prometheus full set (shield break and crit dmg buff) if you have enough crystals. NOTE: Meta is changing, but these valks that I mentioned are the ones in meta right now and covers almost all the bosses. I just started playing last February (Version Kiana), and I can constantly stay in Agony III - Redlotus right now, SSS MA, and Abstinence/Finality Elysian Realm.