Learn how is the rule of 72 derived. Knowing the basic concept and derivation will better equip you to leverage this rule to calculate compounded annual returns (CAGR) in your mind.
Remember: x here is i/100. Take small interest rate, for eg : 8% Then x is 0.08 and x squared is 0.0064 which is very small (compared to x, almost 12 times). But if interest rate is 90%, then x=0.90 and x squared is 0.81 which is not very small compared to x. Consequently, for small interest rates (less than 6%), taking 70 as the numerator would give better results, and 72 for interest rates above 10% gives better results.