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Selectivity in radical chlorination vs bromination of alkanes

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The radical chlorination of simple alkanes is generally much more selective than the analogous radical bromination. Why is it so?
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27 фев 2018

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Комментарии : 13

@dhruv5652 4 года назад

Amazing lecture,

@OrganicChemistryExplained 4 года назад

Thanks, glad it was helpful!

@surajitschemistrylecturefo1360 3 года назад

I understood upto this. But my question is in case of chlorination... Why isobutane gives 63% iso-butylchloride and 37% tert-butyl chloride?

@Himawari-b3n 3 года назад

I know your question's answer

@rannaghoremoumita926 Год назад

Very nice.... but I think you should have drawn two graphs one of primary and secondary radical overlapped to show the difference in energy

@larrenwells2813 5 месяцев назад

Thank you so much!

@hesamb9135 5 лет назад

Thanks for the wonderful lecture

@OrganicChemistryExplained 5 лет назад

No problem, glad you found it helpful!

@lol-ws1gh 4 года назад

great thanks allot

@toukachan7812 10 месяцев назад

nice lecture sir

@mawada-ju6ux Год назад

thank you sir

@glitzandglamourgirl1 5 лет назад

is the selectivity temperature dependant or do we see a difference in selectivity upon increasing temperature?

@OrganicChemistryExplained 5 лет назад

Yes, for kinetically controlled reactions, the selectivity will increase at lower temperature. Below a certain temperature, however, the reaction won't proceed at all.