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Solubility Rules: Explanation & Practice 

Wayne Breslyn
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The solubility rules are important for quickly figuring out is a substance is soluble or insoluble in water. Often students are required to memorize the rules for solubility shown below:
-----
Top rules supersede any lower rules.
In general, salts of:
* Group I elements (Li+, Na+, K+, Cs+, Rb+) are soluble.
* NH4+ are soluble.
* the nitrate ion (NO3-) are generally soluble.
* of Cl-, Br-, and I- are soluble. Exceptions Ag+, Pb2+, and (Hg2)2+
* most sulfates are soluble. Exceptions: Ba2+, Ca2+, Pb2+, Ag+, Sr2+ .
*most hydroxide salts are only slightly soluble. Exceptions: NH4+, Li+, Na+, K+
---
In this video we’ll introduce and practice these rules, building your memory as we go. Then we add several other rules that you’ll see from time to time.
Check with your instructor to see which solubility rules you need to memorize. Some teachers allow you to use a solubility chart but you may still want to have the most common rules memorized.
Note that all compounds are soluble to some degree. If that is a very small amount, we say they are insoluble.
Also note, that when we discuss solubility, remember that solubility is affected by temperature, generally becoming more soluble as the temperature increases.

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24 июл 2019

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Комментарии : 80   
@krishnaswamy6684
@krishnaswamy6684 4 года назад
You explain so well and methodically. I hope students will find these videos. This teacher is awesome!
@wbreslyn
@wbreslyn 4 года назад
Thanks for the kind words! --- Dr. B
@rahmahdalhat8484
@rahmahdalhat8484 4 года назад
It is astonishing how underrated this video...thank you for an amazing effort. Will continue to watch your other videos
@pantone448c0
@pantone448c0 3 месяца назад
Tysm for this great video! My chem teacher just told us that we had to memorize the halide and sulfide exceptions the day before the test 😅 Ong you’re a lifesaver 😁
@aayandadan9340
@aayandadan9340 3 года назад
i was freaking out an hour before my test and you helped me a lot, thanks !
@AK-op4be
@AK-op4be 2 года назад
THANK YOU. you made this so much easier to understand 😭😭😭 ive been struggling with it for the longest.
@ninamurgolo632
@ninamurgolo632 3 года назад
I wish I found these tutorials much sooner in the semester. However, I did benefit by studying for my final as a review. They are clear and to the point, very easy to follow and understand. Thank you
@wbreslyn
@wbreslyn 3 года назад
Glad it was helpful!
@antisymmetric237
@antisymmetric237 5 месяцев назад
I love it. Great job on explaining the steps for solubity.
@mariaarellano8563
@mariaarellano8563 19 дней назад
Thank you Dr. B. What an awesome video :)
@rodolphebourdet959
@rodolphebourdet959 3 года назад
Bonjour, honestly, gorgeous! as french senior I re-start the sciences from the beginning and your videos are so helpful. I do practise both language and siences at the same time. intense but efficient! a big cheer for you. I pray for you :-) Rodolphe
@wbreslyn
@wbreslyn 3 года назад
That is efficient! You get to practice language skills and chem. Very nice!
@rodolphebourdet959
@rodolphebourdet959 3 года назад
@@wbreslyn Dear Wayne, a reliable summarize from you. Clever and delicious! I offer you a great deal of positive thoughts for this wonderful day. 🧘🏿‍♂️💫 Rodolphe
@sanjaygore2107
@sanjaygore2107 19 дней назад
Respected sir Nice .
@crawfordm1589
@crawfordm1589 4 года назад
GREAT VIDEO!!
@curtpiazza1688
@curtpiazza1688 2 года назад
Great lesson!
@jaredguerra9324
@jaredguerra9324 4 года назад
Can you please look up "Table 4.1 Solubility Guidelines for Common Ionic Compounds in Water" and explain why the diffference in solubility for CaSO4, AgSO4, and Ca(OH)2. I saw the solubility table showed slightly soluble for the first 2 and the last one is a strong base of group 2A metal hydroxides. I just need closure on the matter of why not soluble?
@zoyasayyyed.2
@zoyasayyyed.2 2 года назад
Thank you so much sir ❤️ Because of you I can score good marks in my chemistry exams ❤️😭 thank youu ❤️ a warm thank you ❤️🥰
@kaholeung9443
@kaholeung9443 3 месяца назад
very useful , thank you
@activeman464
@activeman464 Год назад
شرح ممتاز Perfect teacher
@wbreslyn
@wbreslyn Год назад
Thanks!
@antisymmetric237
@antisymmetric237 5 месяцев назад
Thank you.
@user-cx7kb9lp5e
@user-cx7kb9lp5e 10 месяцев назад
Thanks Dr B you really help me with your explanation😊
@wbreslyn
@wbreslyn 10 месяцев назад
Excellent!
@user-wn5mv8bs6x
@user-wn5mv8bs6x 4 месяца назад
Good sir
@maxarnd
@maxarnd 3 года назад
Gran video! Saludos de Perú xdd
@wbreslyn
@wbreslyn 3 года назад
Thanks!
@bunny4173
@bunny4173 2 года назад
DR B . thanks for the video .anyway is there any explanation as to why these salts are insoluble ? like AgCl etc
@wbreslyn
@wbreslyn 2 года назад
That is really the important question! There is a good discussion at www.reddit.com/r/askscience/comments/3mjewb/why_are_some_salts_insoluble/ It's not an easy question to briefly answer.
@hassanbaksh5279
@hassanbaksh5279 Год назад
Sir, At 7:27 you were saying exceptions are NH4+, Li+, Na+ and K+ but after that you said they will be (aq)
@wbreslyn
@wbreslyn Год назад
Hmmmm. Group 1 elements (Li, Na, K) and NH4+ are almost always soluble. So compounds with these should be soluble according to the solubility rules.
@hassanbaksh5279
@hassanbaksh5279 Год назад
@@wbreslyn Thanks sir
@shanimap2721
@shanimap2721 4 года назад
Thank u sir
@wbreslyn
@wbreslyn 4 года назад
Welcome!
@ruthbeisheim8299
@ruthbeisheim8299 Год назад
Is your solubility table that you reference in your videos available for download?
@wbreslyn
@wbreslyn Год назад
Here is the full version of the table I use: en.wikipedia.org/wiki/Solubility_chart
@shivamsikotra3733
@shivamsikotra3733 3 года назад
very good video
@wbreslyn
@wbreslyn 3 года назад
Thanks!
@victoriaogedegbe4931
@victoriaogedegbe4931 3 года назад
So some rules says “all metals” but what if some had non metals in it. Like rule 3. If nitrate had a non metal with it, is it soluble?
@wbreslyn
@wbreslyn 3 года назад
I would suppose so. NH4NO3 certainly would be. But since the nitrate ion has a 1- ionic charge it doesn't bond with non-metal ions which are negative.
@ranamuruodedara183
@ranamuruodedara183 3 года назад
Good👍👍
@wbreslyn
@wbreslyn 3 года назад
Thanks!
@leighannesantos3334
@leighannesantos3334 2 года назад
where's the link for the practice? and thank you for this vid!
@wbreslyn
@wbreslyn 2 года назад
Happy to help! In this case it's embedded in the video (that's why is longer than my usual videos). You can probably find many other videos I made by searching on "is _______ soluble or insoluble". For example "is CaSO4 soluble or insoluble".
@devaiahkodira8596
@devaiahkodira8596 4 года назад
Sir give examples of which elements are solid, liquid,gas and aq.
@yasyasmarangoz3577
@yasyasmarangoz3577 3 года назад
Do you need any help?
@devaiahkodira8596
@devaiahkodira8596 3 года назад
@@yasyasmarangoz3577 s plz
@yasyasmarangoz3577
@yasyasmarangoz3577 3 года назад
@@devaiahkodira8596 Ok ROOMTEMPERATURE: Fe(s) H2O(l) H(g) NaCl in Water is NaCl(aq)
@devaiahkodira8596
@devaiahkodira8596 3 года назад
@@yasyasmarangoz3577 wow thank you it helps a lot
@yasyasmarangoz3577
@yasyasmarangoz3577 3 года назад
@@devaiahkodira8596 Your welcome, it makes me happy to know that I've helped someone👍
@electro_yellow9295
@electro_yellow9295 3 года назад
Wait how is PbI2 not soluble but in the rules it it says that I- is soluble and PbI2 has an iodide in it?
@wbreslyn
@wbreslyn 3 года назад
PbI2 is one of those exceptions. If you see Pb or Ag be careful! Check the rules in the video. You'll see it Pb there.
@tristango1685
@tristango1685 2 года назад
Why is NaOH soluble? Isn’t hydroxide an exception when it comes to solubility?
@wbreslyn
@wbreslyn 2 года назад
Group 1 elements, like Li, Na, K hydroxides are soluble. Sort of an exception.
@ARGAMING-vz2jc
@ARGAMING-vz2jc 3 года назад
I AM FROM BANGLADESH🇧🇩
@wbreslyn
@wbreslyn 3 года назад
Awesome!
@SS-rb5ys
@SS-rb5ys Год назад
you are a great teacher, I understand everything and the solubility rules thanks to you! your teaching makes everything easy and understandable! Thank you
@wbreslyn
@wbreslyn Год назад
Thanks for the kind words!
@henripavot4492
@henripavot4492 2 года назад
But why ARe the solubles solubles ? This is what would be interesting to know. Can you explain ? Thank you.
@mikeboyd1961
@mikeboyd1961 2 года назад
Group 1 always soluble because their charge is only 1+. Once you get 2+, 3+ and greater the solubility decreases. More charge means stronger ionic bonding and lower solubility. Similarly for the anions. Halides generally soluble as 1-. CO3 2- & PO4 3- generally insoluble except when with monovalent cations ie group 1 and the ammonium ion. NOW you are going to ask what about OH- ion which seems to be an exception. I think this is partially down to charge to mass ratio but am guessing a little. Mol wt OH- is 17. Cl- 35.5, CO3 2- 60, PO4 3- 95. I am fairly sure that there will be other effects as well. Quantum effects and Nuclear Resonance Effects maybe? We need more help from the experts!
@huzaifaabedeen7119
@huzaifaabedeen7119 2 года назад
What are the prerequisites for this video??
@bunny4173
@bunny4173 2 года назад
Famialiarity with general chemistry ... U can find many good books on gen chem ... Like chemistry the central science
@MigzAztig21
@MigzAztig21 Год назад
is aluminum trichloride solube in water?
@wbreslyn
@wbreslyn Год назад
Oh yeah. solubility in water 439 g/L (0 °C) 449 g/L (10 °C) 458 g/L (20 °C) 466 g/L (30 °C) 473 g/L (40 °C) 481 g/L (60 °C) 486 g/L (80 °C) 490 g/L (100 °C) en.wikipedia.org/wiki/Aluminium_chloride
@ZUCULENTOZOPRO
@ZUCULENTOZOPRO 4 года назад
thanks sir
@wbreslyn
@wbreslyn 4 года назад
Most welcome!
@susmitamondal4824
@susmitamondal4824 2 месяца назад
Sir, Can you please explain Why Francium(Fr) is not included in the first statement?
@wbreslyn
@wbreslyn 2 месяца назад
It is radioactive and doesn't stay around for very long.
@EcoTravelDiscoveries
@EcoTravelDiscoveries 4 года назад
I didn't understand why did you say that calcium hydroxide is insoluble? (7:34)
@wbreslyn
@wbreslyn 4 года назад
Ca(OH)2 is relatively insoluble in water, sometimes listed as slightly soluble. All compounds will dissolve at least a small amount but if it is very small we call it insoluble. --- Dr. B (see en.wikipedia.org/wiki/Calcium_hydroxide)
@huzaifaabedeen7119
@huzaifaabedeen7119 2 года назад
Where is the link to practice videos sir??
@wbreslyn
@wbreslyn 2 года назад
That is a good question! I don't think I ever made that video (I'll put it on my list). But this video might be of help: ru-vid.com/video/%D0%B2%D0%B8%D0%B4%D0%B5%D0%BE-snxoegzVnWw.html
@huzaifaabedeen7119
@huzaifaabedeen7119 2 года назад
@@wbreslyn thank you Dr. B for your reply. Are the solubility rules applicable for water only or for any solvent?
@wbreslyn
@wbreslyn 2 года назад
@@huzaifaabedeen7119 Good question! They apply to water only.
@pi4313
@pi4313 Год назад
my chart looks different than yours
@dreclawwoo9615
@dreclawwoo9615 10 месяцев назад
Then a duel must be set to decided which one has the true chart in the old roman ways, when and where is the only question you need to ask. FOR ONLY 9.99!!! (i am losing braincells)
@pi4313
@pi4313 10 месяцев назад
@@dreclawwoo9615 lol
@user-wn5mv8bs6x
@user-wn5mv8bs6x 4 месяца назад
Ma ka
@hamzabaig8856
@hamzabaig8856 Год назад
If only you were my chemistry teacher .... You're one of a kind. 🥸😄
@hamzabaig8856
@hamzabaig8856 Год назад
TY!
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