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Steric and electronic factors modifies the Baldwin rules at times. 3-endo-Tet reaction should be disfavored. Such reactions do not form a ring, but appear to pass through a cyclic transition state leading to the cleavage of a sigma bond, while a new sigma bond is formed. I hope you understand why it happens
In the [2,3] Steven’s rearrangement, how a nucleophic carbanion attacks the double which is also rich in electron density. Why not [1,2], because of near quaternary nitrogen
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