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The zeroth law of thermodynamics states that if two thermodynamic systems are each in thermal equilibrium with a third one, then they are in thermal equilibrium with each other. Accordingly, thermal equilibrium between systems is a transitive relation.
Two systems are said to be in the relation of thermal equilibrium if they are linked by a wall permeable only to heat and they do not change over time.[1] As a convenience of language, systems are sometimes also said to be in a relation of thermal equilibrium if they are not linked so as to be able to transfer heat to each other, but would still not do so (even) if they were connected by a wall permeable only to heat.
The physical meaning is expressed by Maxwell in the words: "All heat is of the same kind".[2] Another statement of the law is "All diathermal walls are equivalent".[3]
The law is important for the mathematical formulation of thermodynamics, which needs the assertion that the relation of thermal equilibrium is an equivalence relation. This information is needed for a mathematical definition of temperature that will agree with the physical existence of valid thermometers.[4]
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18 янв 2020
