Every Clone Trooper That DISOBEYED Order 66 (Canon) 

Do not worry soldier you’re secret is safe with us!

Time to send the torture droid.

@@Louthedrone we got a imperial spy.

@@Kai-the-ninja-of-fireee they try anything and they’re gonna be eating thru a straw

Sheesh

Based on his interaction with Rex and Hunter from season 3, I speculate Rex later reached out to him to meet for a further discussion which lead to Wolfe's removal of his inhibitor chip. So he technically didn't disobey Order 66, but didn't follow it either since there were no more Jedi left for him to pursue. We know the chips have a shelf life of approximately 6 months before the clones regain their sense of agency once more (Commander Cody deserting the empire after his last mission with Crosshair). Wolfe most likely aged out the true potency of the chip.

I’m not sure myself, but seeing as Tup (the one who executed Order 66 early) only got violent towards Masters Tiplar and Tiplee, but not towards Anakin, makes it seem they were somehow made to target any Jedi but Anakin. I don’t know how this could’ve been done exactly, since Anakin was just a boy when the clones were first created, but I wouldn’t put it past Palpatine to have created Order 66 to work this way.

Isn't it obvious? The emperor would have kept Anakin off the kill list and likely made that a seperate order. In fact it's established in the comics that there's an order for the stormtroopers to attack Vader if he gets out of line.

@@taramaforhaikido7272 Except also in the comics, CG Troopers fired on Vader assuming he was a Jedi for Order 66. Though Fox had not made his men aware he was not to be fired upon.