Whenever I Say Your Name - Sting and Mary J Blige (2003) 

From the DVD Sting Inside The Songs of Sacred Love, A&M Records 2003.
This is one of those performances that are so good you get goose bumps.
"Whenever I Say Your Name" is a duet by English musician Sting and American singer Mary J. Blige. It serves as the second single from Sting's seventh studio album Sacred Love (2003). It was not originally included on Blige's sixth studio album Love & Life but was later added to the album's international re-release. The recording won Best Pop Collaboration with Vocals at the 46th Grammy Awards in 2004.
The undeniable Mary J. Blige oozes exuberance on “Whenever I Say Your Name.” Both Blige and Sting take the opportunity to play to their strengths. Sting begins the tune with a characteristically moody, subtle verse. Imperceptibly, the song morphs into a borderline funk romp, pushing Blige’s power vocals to the fore.