Introductory Quantum Chemistry by Prof. K.L. Sebastian, Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore.For more details on NPTEL visit nptel.iitm.ac.in
Sir, I want to ask that if we apply this orthogonality of functions to the previous argument of probability (at 17:00) with linear combination then how is it being time dependent valid?
Perhaps bcz V was not actually 0..it was our assumption...V was very less compared to the infinite V of the surroundings but was having some less finite value.
Maybe bcoz we are considering time dependent case which is only possible when V is also a function of time that's why it's varying inside box and is symmetric
