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Radical Substitution Mechanism 

MaChemGuy
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Description of reaction between methane and chlorine

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4 авг 2024

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Комментарии : 58   
@enacausmembrane
@enacausmembrane 3 месяца назад
When this video came out, I was still learning about multiplication tables. 10 Years later, I finally understand this video.
@henersinsane
@henersinsane 8 лет назад
most helpful internet chemistry teacher ever, much better than trolling through revision site, THANK YOU!
@MaChemGuy
@MaChemGuy 8 лет назад
+Henry Lawrence Wow, that's nice of you to say. Thanks!!
@junnurinhasan3699
@junnurinhasan3699 8 лет назад
Better than my school teacher, thanks!
@shazkhan5392
@shazkhan5392 9 лет назад
Couldn't be more clear. Well explained.
@MaChemGuy
@MaChemGuy 9 лет назад
Shaz khan Thanks a lot for taking the time to comment
@THE1ANDONLYTWEETY
@THE1ANDONLYTWEETY 8 лет назад
Oh Gosh, wish I'd have found this channel sooner as I have my exam at 1400 today!Very well explained. Cheers Sir.
@RyuFan1999
@RyuFan1999 8 лет назад
Finally found this gem of a channel through intense searching.. THANK YOU SIR!
@MaChemGuy
@MaChemGuy 8 лет назад
Wish there was an easy way for me to get the message out. Am constantly tweeting about the channel but only seem to be noticed by a very small number of new students. Thank you by the way!
@RyuFan1999
@RyuFan1999 8 лет назад
No problem, I'm going to do my part as a viewer and get your channel known in my class. Thanks for your support
@bobbyjohnson9459
@bobbyjohnson9459 3 года назад
I was in year 6 of primary school when this video was made and I’m now using it to revise for my chemistry test tomorrow morning. Thank you
@MaChemGuy
@MaChemGuy 3 года назад
Thanks for that 😬
@pokemasterx4244
@pokemasterx4244 3 года назад
Lol u were probably in year 7, cus 2015
@paulbailey1927
@paulbailey1927 9 лет назад
I found this a really useful tool to refresh my memory at times throughout the year and just before my exams now I get full marks on all three of the mechanisms every time. Cheers, it's appreciated
@lucyjarvis9420
@lucyjarvis9420 8 лет назад
By far the best revision channel I've come across, thank you so much!!
@MaChemGuy
@MaChemGuy 8 лет назад
Very kind of you to say so. Thanks!!
@07caitlinr
@07caitlinr 9 лет назад
I finally understand this now! Thank you so much :)
@Sibasish07
@Sibasish07 7 лет назад
Just amazing explanation.. that's called experienced teacher...thanks sir
@abdimalikali6429
@abdimalikali6429 8 лет назад
great explanation, really needed this . thanks.
@asifhussain7097
@asifhussain7097 9 лет назад
amazing, i wont forget it now :)
@chrys9244
@chrys9244 7 месяцев назад
Thank you so much for this, you're literally saving me with all of your videos 😊
@MaChemGuy
@MaChemGuy 7 месяцев назад
👊👊👊
@Ishaalsariff14
@Ishaalsariff14 3 года назад
So well explained i must say!
@sumayyahaisha2068
@sumayyahaisha2068 7 лет назад
very well explained, thank you very much :)
@leviathan24_
@leviathan24_ 7 лет назад
Why does the cl radical take the H and not anything else in p1? Is it because h has one outer electron to bind with the unpaired electron In the cl outer shell?
@hemoisthebestemo1234
@hemoisthebestemo1234 7 лет назад
thank you soon much! I really appreciate the time you took doing this video! it helped me A LOT! god bless you
@MaChemGuy
@MaChemGuy 7 лет назад
elham f.m You're very welcome. Thanks for the comment
@ahmadtheaviationlover1937
@ahmadtheaviationlover1937 2 года назад
i have to admit a level chemistry has to be one of the hardest subjects to study, i dropped out of chemistry and did physics which i got a B at the end
@mohfa1806
@mohfa1806 3 года назад
very nice video and explanation , my question is why the radical ch3 doesnt react with the stable ch4?...thx
@physicsimpossible73
@physicsimpossible73 8 лет назад
I found it a bit misleading how the dot is not over the carbon atom but apart from that it was well explained
@MaChemGuy
@MaChemGuy 8 лет назад
+Epicnerd73 Kind of you to say so. OCR don't even bother with the dots to be honest. All of the mark schemes say 'Ignore dots'
@physicsimpossible73
@physicsimpossible73 8 лет назад
MaChemGuy Oh I see, kind of weird. My exam board is AQA, I don't know if they are the same..
@MaChemGuy
@MaChemGuy 8 лет назад
+Epicnerd73 Check with your Chem teacher
@yuvishanmanimaran6813
@yuvishanmanimaran6813 Год назад
@machemguy thank you for the video it is very helpful. Please could you explain why at step P2 does the methyl react with chlorine. Could it not react with more methane instead? Thanks!
@physchemwithliz5879
@physchemwithliz5879 Год назад
In the 2nd propagation step, it is always an alkyl radical reacting with a halogen 🙂 The alkyl radical is an intermediate (something reactive that is formed in one step and used up in a subsequent step), hope that helps
@SilverLeguar
@SilverLeguar 7 лет назад
how many termination steps would there be is theres excess Cl2
@darieldiaz2106
@darieldiaz2106 7 лет назад
1
@daisytucker4498
@daisytucker4498 3 года назад
hey sir i hope you are doing well. thanks for the effort you put into the videos. i have a questions if you don't mind. could you summarise the problems with radical substituion if possible ? thanks
@MaChemGuy
@MaChemGuy 3 года назад
Substitution can occur anywhere on the carbon chain Multiple substitutions are possible (if halogen in excess) There is more than one termination step
@daisytucker4498
@daisytucker4498 3 года назад
@@MaChemGuy thank you. last question if you may. does a double oxygen bond on a carbon affecr solubility or only oh groups?
@MaChemGuy
@MaChemGuy 3 года назад
@@daisytucker4498 The H of a water molecule can interact with the O of a C=O. However, the H and the O of a water molecule can interact with a hydroxyl group. In other words, OH groups are more significant
@thomasstokes5799
@thomasstokes5799 4 года назад
At 6:47 why does the chlorine radical take a hydrogen opposed to the chlorine?
@MaChemGuy
@MaChemGuy 4 года назад
Thomas Stokes Probably down to fact that more energy is released by the H-Cl bond than the Cl-Cl bond. More likely to form therefore
@neilhughes07
@neilhughes07 5 лет назад
Would further substitution be a limitation of radical substitution, and if so, could you please explain why? Thank you in advance
@MaChemGuy
@MaChemGuy 5 лет назад
Lucia Hughes Yes as well as substitution can occur anywhere on the carbon chain (if it’s got >2 C atoms). Basically if there’s excess halogen present there will be a large amount of halogen radicals present in the reaction mixture. These can strip out multiple H atoms (via a pair of propagation steps for each one). Hope that makes sense. Due to this, it’s very difficult to only make the desired product
@MaChemGuy
@MaChemGuy 5 лет назад
Lucia Hughes see last couple of mins of this one too ru-vid.com/video/%D0%B2%D0%B8%D0%B4%D0%B5%D0%BE-n9MCZJMrkc8.html
@neilhughes07
@neilhughes07 5 лет назад
That was very helpful thank you v much!
@MaChemGuy
@MaChemGuy 5 лет назад
Lucia Hughes You’re very welcome. Keep watching!
@ameliastephens7528
@ameliastephens7528 3 года назад
Why does the methyl become a radical?
@MaChemGuy
@MaChemGuy 3 года назад
It has an unpaired electron when the chlorine radical takes the hydrogen (and electron)
@noorah.r8411
@noorah.r8411 7 лет назад
Wouldn't the free electron be on the carbon and not hydrogen in methyl? so .Ch3 not Ch3.
@callumbrown8135
@callumbrown8135 6 лет назад
mxhnoor _ the whole molecule has a negative charge of -1
@WwSugarCreekwW
@WwSugarCreekwW 7 лет назад
You didn't show the mechanism...
@MaChemGuy
@MaChemGuy 7 лет назад
Jonathan Lopez The whole video is the mechanism
@darieldiaz2106
@darieldiaz2106 7 лет назад
Actually, the arrows showing the moving of electrons is the definition if the mechanism... What you showed was not the mechanisms....
@razor0mind
@razor0mind 7 лет назад
Dariel Diaz there are different ways to represent the mechanism depending on the kind of reaction, electrophilic and nucleophilic attack uses the movement of electron pair model. Whereas with radicals there are no electron pairs moving, they are singular elections so they have this model instead. Only correct a teacher when your positive you're right. In this case you are not.
@smallken248
@smallken248 6 лет назад
silly yank
@RuhabDabeer
@RuhabDabeer 5 лет назад
Very Annoying to remember that Propagation step
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