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Recrystallization 

Professor Dave Explains
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Now that we have covered a variety of separation techniques, we know how to get an isolated product! But if it's a solid, it may contain impurities. Recrystallization is a common organic chemistry laboratory technique for the purification of solids, so let's learn how to do it!
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29 сен 2024

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Комментарии : 146   
@danielh.8602
@danielh.8602 4 года назад
Thank you very much for the video, I'm using this method in my organic chemistry lab. but most explanations went much more in depth than I needed and I had harder time understanding how this process worked than was necessary. This helped me quite a bit.
@jocelynjarro9873
@jocelynjarro9873 10 месяцев назад
thank you so much! i am reviewing for my practical exam and this video helped me a ton :)
@EtherealRoninERProductions
@EtherealRoninERProductions 2 года назад
Basically a summary of practical 10 pretty much, in a level Edexcel chemistry But yeah the practical is preparation of a pure organic solid and test of its purity and then the second part of it is preparation of a pure organic solid
@chair547
@chair547 2 года назад
If the impurities are able to interrupt the lattice structure during the original precipitation, why aren't they also able to during the second step
@HIGHER7RUTH
@HIGHER7RUTH 2 года назад
Because they aint as gangster lol
@lcchen3095
@lcchen3095 Год назад
Was thinking the same.
@atrumluminarium
@atrumluminarium Месяц назад
Because they are more dilute. Lets take an example: A precipitate was obtained from a solution containing A and B at 1:1 molar ratio. Let's say we precipitate A but maybe 1% of B got caught in A's crystals. Using fresh solvent we redissolve A's crystals and this makes a new solution with ratio 100:1 If you repeat and 1% get caught up in the crystals, this time it will be 1% of 1% so the new amount of impurities will be down to 0.01%
@sonusharma6116
@sonusharma6116 4 года назад
Thank you sir
@gopalkrishna3956
@gopalkrishna3956 3 года назад
Tnx so much I gone using this method in my exam😍😍
@orantesjimmy
@orantesjimmy 4 года назад
Hello, so hot solvent is used to wash the recrystallized product in the filitration step?
@nzadventurefamily3728
@nzadventurefamily3728 4 года назад
Use cold solvent to wash away any impurities from the recrystallised product without dissolving it.
@sirawesomeness7543
@sirawesomeness7543 Год назад
No that would dissolve it again and it would go through the filter 🤦🏼‍♀️ you want to keep the crystals on the filter
@josephgithinji1490
@josephgithinji1490 4 года назад
First!
@zainrabee2675
@zainrabee2675 4 года назад
No 🤣
@zainrabee2675
@zainrabee2675 4 года назад
Where are you from?
@noah19123
@noah19123 Год назад
thank you chemistry jesus
@Michael_Jackson187
@Michael_Jackson187 4 года назад
Dmt
@ingridfellows6468
@ingridfellows6468 2 года назад
Thanks! Engaging videos for my college lab students since we are virtual.
@angeldiaz8197
@angeldiaz8197 3 года назад
And that’s how you cook crack Ladies and gentlemen !
@isaackalashnikov3681
@isaackalashnikov3681 3 года назад
No, crack is made by mixing cocaine with sodium bicarbonate in hot water and then evaporating all the water
@oliverbullmann6176
@oliverbullmann6176 6 месяцев назад
@@isaackalashnikov3681wrong Ehen you do this method you will have the hole Salt in the free base !!! You use bicarbonite and Wait since the freebase Fall out and than throw the water away and dont evapoate it or use Ammoniak thats the purest Crack cokain But you should Wasch the Rest of Ammoniak out with water and the Street recept is to mix the coke powder with bicarbonate and but the dry powder into a microwave and Cook it thats dry cooking and you have more wight for the blackmarkwt because the hole bicarbonate Salt is in it 😂😂😂!
@chrisgunter1878
@chrisgunter1878 2 года назад
This was useful for quickly remembering how to do something I learned how to do last semester.
@WalkinWhiskey
@WalkinWhiskey 5 месяцев назад
THANK YOU, MAN, my manuals are mystery novels. I always wanted to know why dissolve at high temp but not at low temp, so what i got from this is that at low temperature, the solid is supposed to crystalize, and at high temperature it's supposed to dissolve. And that the impurities should dissolve at room temp so they stay dissolved and don't precipitate. Am i wrong?
@prescillaromero8775
@prescillaromero8775 2 года назад
Thank you! That was so informative and straight to the point
@guillermorodriguez4873
@guillermorodriguez4873 Год назад
Could you explain me how to get MCT oil from cocunut oil ? Step by step....
@CaseyFinSF
@CaseyFinSF 4 года назад
Ahhhhhh the Meth Episode.... was wondering when you'd get around to this🤫😳🤯
@SWRfrfr
@SWRfrfr 2 года назад
Breaking bad (real)
@williamolson55
@williamolson55 Год назад
He explains it in a very non meth way
@himanshirohilla-ur8wn
@himanshirohilla-ur8wn 4 года назад
thankyou so much for such a nice explanation as I m preparing for my practicals so it helped me a lot
@BayanKawani.5
@BayanKawani.5 5 месяцев назад
لاالەالااللە
@Mr.absalom
@Mr.absalom 4 месяца назад
You should explain the content by giving examples 🤦🏽‍♂️ of the solute and solvent
@NellvinCervantes-gt4ot
@NellvinCervantes-gt4ot 2 месяца назад
Then what will happen to the seed crystal when it is applied after filtration. Seed crystal lowers potential energy barrier to nucleation to happen that creates template to be absorbed by atoms, ions or molecules to form an arrangement as of crystals. This seems that the purified crystal after crystallization and seed crystal are bonded together after filtration. So it seems the 'purified' crystal isn't totally purified as it has seed crystals mixed in it. 🤔
@SingleMommyOf3
@SingleMommyOf3 4 года назад
hopes this helps me make thc-a
@chasedavis2358
@chasedavis2358 3 года назад
Helps with dmt too
@nicholasgold4881
@nicholasgold4881 3 года назад
Helps to make high purity bleach crystals from a bleach solution on hand, for storage and longevity of the now pure stable and solid form of Sodium Hypochlorite. My question would this make the sodium Hypochlorite crystals a salt base or HCL solid?
@zezaomachado
@zezaomachado 2 месяца назад
Nice matther. But I am looking for something such similar but at the organic field. Precisely to try and polite the crystals of my eyes cataract disease than to submit to implant artificial lens surgery.
@itsrusul
@itsrusul 4 года назад
ما عبالك استاذ ، شكد مرّح 😂💙
@lorriecarrel9962
@lorriecarrel9962 2 года назад
I like watching your vids,you are very intelligent
@tejas517
@tejas517 4 года назад
Can u pls tell me how to separate the small qty of compound in mother liqour which didnt form crystals but was supposed to??
@SonamKumari-zu6sg
@SonamKumari-zu6sg 4 года назад
❤️❤️Love from India 🇮🇳🇮🇳
@tylerkutschbach
@tylerkutschbach 4 года назад
What day this month will you do Woodrow Wilson
@dalemyers119
@dalemyers119 Год назад
So I just learnt how to make Crack Cocaine....
@xOxAdnanxOx
@xOxAdnanxOx 4 года назад
the choice of the solvent will be based more on the identity of the impurities? So they will not recrystallize again with the pure solid?thank you
@davidblack4195
@davidblack4195 3 года назад
Solids usually have different temps that they crystallize at. Know your temps for the main ingredient you want to keep and your problem is solved
@christinemohanna2846
@christinemohanna2846 8 дней назад
You are the best. Thanks for all of your videos. You have a special technique to help students understand Chemistry. Thank you!
@arishbamemon8929
@arishbamemon8929 2 года назад
Why is it necessary for the solvent to have low solubility at room temperature? can someone please explain
@ProfessorDaveExplains
@ProfessorDaveExplains 2 года назад
So that the product will precipitate again. Otherwise it will just stay in solution and you can't collect it.
@arishbamemon8929
@arishbamemon8929 2 года назад
@@ProfessorDaveExplains thank you! that makes it clear.
@nunyabisnass1141
@nunyabisnass1141 11 месяцев назад
It's not necessary, it's just taking advantage of the fact that solids have specific solubility that correspond with temperature. "Room temperature" is just a standard reference like zero is between 10, and -10. For example, chlorates have a very low solubility versus chlorides at 0°C, which is much lower than room temp. On the other hand oxides may have no solubility until say 1,500°C. It just depends on what you're trying to do, but most crystals are nitrates, sulphates, or chlorides, and those are easiest to manipulate at 25°C (room temp).
@Song-cj6rl
@Song-cj6rl Год назад
Having my lab test tomorrow life saver 🎉thank you very much!
@Bbriamalupa
@Bbriamalupa 4 года назад
Is sugar crystal with thread on it. Is a result of cooling or evaporative crystallization????
@abarnaj3683
@abarnaj3683 3 года назад
Sir, My crude extracts from bacteria but it's dissolved only In water pls tell me what can I do sir
@madskillproduction
@madskillproduction 2 года назад
Thanks!
@pokemonjynx1019
@pokemonjynx1019 8 месяцев назад
how did you remove the impurity? did they just evaporate? or did you phyiscally remove them?
@luxintelligentia4632
@luxintelligentia4632 2 года назад
If i had a pill or other form of some medicine, can i crystalize it like this or is anything going to crystallize?
@iamsonedisoncahaya4845
@iamsonedisoncahaya4845 Год назад
I'm suck at recrystalitation, but good at Preperation.
@Fefeknows
@Fefeknows 4 года назад
You are phenomenal
@gyoseph8679
@gyoseph8679 3 года назад
CHEM 2511 (Organic) online lab tomorrow yessir 😁
@yoonkittybruh8275
@yoonkittybruh8275 3 года назад
Thank you very much !
@zz-dd1eo
@zz-dd1eo 5 месяцев назад
thanks king
@kaeceedancel9066
@kaeceedancel9066 3 года назад
Is it necessary to cover the beaker containing the benzoic acid solution while cooling down?
@mohamadhanan5706
@mohamadhanan5706 4 года назад
I have an exam in this tomorrow! So thanks pro
@rassimsimou1594
@rassimsimou1594 2 года назад
Good
@rambiharibhaiprajapati2000
@rambiharibhaiprajapati2000 3 года назад
I need in hindi language
@tarahclue6737
@tarahclue6737 2 года назад
thank you
@TikTokkidunya148
@TikTokkidunya148 4 года назад
Thanks sir
@zainrabee2675
@zainrabee2675 4 года назад
Hallo
@TikTokkidunya148
@TikTokkidunya148 4 года назад
@@zainrabee2675 yes
@zainrabee2675
@zainrabee2675 4 года назад
Where are you from?
@amitmohanty376
@amitmohanty376 3 года назад
Phthalimide is recrystallize in which solvent ?? Sir.
@rube7103
@rube7103 2 года назад
🙃🙃 thank you for helping me learn something usuf
@affentat8723
@affentat8723 Год назад
Thank you so much for breaking it down to the basics! ^^
@fakhrulnawawi9681
@fakhrulnawawi9681 4 года назад
Stirring rod or spatula?
@ProfessorDaveExplains
@ProfessorDaveExplains 4 года назад
glass stirring rod
@guillermorodriguez4873
@guillermorodriguez4873 Год назад
Could you explain me how to get MCT oil from coccunut oil..? Step by step .. Wich method..
@nunyabisnass1141
@nunyabisnass1141 11 месяцев назад
You first have to go find the literature on that product and identify it's properties. If it's an oil then a non polar solvent is often good enough, but some behave differently when it's an organic vs inorganic solvent, so that may be important. So after choosing the best available solvent then try to identify other components that may carry over with it, and the properties of those to see which can be separated with the methods available. I'm not familiar that compound so I can't tell you a specific method.
@petika654
@petika654 4 года назад
Thanks for video. Very helpful before my practical exam, so to remind me how it all works. Thanks a lot.
@c2kdkr163
@c2kdkr163 3 года назад
can we use water as a solvant here? I want to make that experiment
@sudipghorai3783
@sudipghorai3783 Год назад
Sir,is it is mandatory to dry the crude product completely before recrystallization,which i want to recrystallized?
@nunyabisnass1141
@nunyabisnass1141 11 месяцев назад
No. The general principle is just reducing the solubility to a point where the solvate is less soluble than the impurities. Crystalization of the appropriate product is best as a first step where it applies, but not all products crystylise in the same fashion or even in a practical means. One such method is dissimilar separation, where you use two different solvents that won't mix, but the product and impurities are more attracted to one than the other. This is usually a method to separate organic and inorganic molecules, but is also useful between polar and non polar molecules.
@omsingharjit
@omsingharjit 3 года назад
Can it also removes Colour ?
@shercon2522
@shercon2522 Год назад
So...a NATURAL gemstone with inclusions can be recrystallized and become a clean gemstone? If yes....what will be the teal difference between the natural stone BEFORE the process and AFTER the process? After the process, can it still be called a NATURAL gemstone??
@ProfessorDaveExplains
@ProfessorDaveExplains Год назад
The composition. And... yes? I'm not sure.
@nunyabisnass1141
@nunyabisnass1141 11 месяцев назад
Let's take quartz or Rudy (corundum) as an example. No, they would after the e process be considered lab grown or artificial, even if you dissolved naturally harvested components and used a seed crystal to kickstart the process. The reason is because they were altered and remade in a lab.
@pokemongo6077
@pokemongo6077 4 года назад
Ah, It's 800th video!!
@jpjacobs3425
@jpjacobs3425 2 года назад
do you have any videos on basic chemistry? because I don't really know sht
@ProfessorDaveExplains
@ProfessorDaveExplains 2 года назад
Yes, watch my general chemistry playlist from the beginning.
@zackzimmer7167
@zackzimmer7167 2 года назад
Is it me or is he flexing his tattoo?
@santicruz4012
@santicruz4012 3 года назад
What happens if you cool it down too quickly?
@Dump51
@Dump51 Год назад
Does this work for drugs?
@pranavmorey4551
@pranavmorey4551 3 года назад
I am trying to make 3 Nitro phthalic acid, but during the purification the crystals doesn't get formed as we expect. The. Crystal sizes are pretty smaller than the standard ones. Please help.
@davidblack4195
@davidblack4195 3 года назад
Drop strings into the solution and let them form onto the string
@herman58100
@herman58100 Год назад
What solvents can be used?
@Rauchgestein
@Rauchgestein 4 года назад
Fucking love your Intro man
@RinaNewhouse
@RinaNewhouse 2 года назад
You saved me for my lab practical tomorrow!!!
@saaaah5504
@saaaah5504 2 года назад
professor dave supremacy
@VEERAPAAN-GAMING
@VEERAPAAN-GAMING 2 года назад
Hello sir I am from India
@nurbaiti6820
@nurbaiti6820 3 года назад
Bagus bang videonya, makasi 😘
@PrakashPulse4573
@PrakashPulse4573 2 года назад
Thank you sir
@giftsibiya
@giftsibiya Год назад
Thanks! My question is, is possible to recrystallise without heating a solvent?
@alexwang982
@alexwang982 Год назад
Yes, evaporative
@nunyabisnass1141
@nunyabisnass1141 11 месяцев назад
Yes, there are a few ways, but it depends onr he properties of the solvate. As someone said evaporation of the solvent is one method, which requires either heating or dehydration by some method. One method is to add a solution of another chemical that has a higher affinity with the solvent than the product, and that will reduce the solubility of the product and cause it to crash or precipitate out, although requiring additional purification steps.
@yugendhirannagaraj241
@yugendhirannagaraj241 3 года назад
By the way the video is helpful
@kataraarts3027
@kataraarts3027 2 года назад
OMG THANK YOU!! This is perfect
@nazninakhter2883
@nazninakhter2883 Год назад
Thanks
@alhassanmichael306
@alhassanmichael306 2 года назад
Woooow 👏👏👏
@zeshaanahmad2768
@zeshaanahmad2768 2 года назад
nice
@K.A.F_69
@K.A.F_69 3 года назад
Nice
@stephendaniel9581
@stephendaniel9581 2 года назад
How does one not blow up solvent when heating it up?
@ProfessorDaveExplains
@ProfessorDaveExplains 2 года назад
Blow up?
@RTU-mw8ft
@RTU-mw8ft 4 года назад
hi @Professor Dave. I really need your help. I have no idea how to study maths for IIT/JEE. Please start a playlist for that too just like you are doing for Chemistry. Plzzz sir. I have subscribed to all your 4 channels. You are amazing!!!!!!!!!
@ignatievgorodi7470
@ignatievgorodi7470 4 года назад
thanks boss
@Abhi-ph4ks
@Abhi-ph4ks 2 года назад
Thank you sir.
@unlockeduk
@unlockeduk 2 года назад
sweet now i can recrystallize my meth from powder to real crystals
@god-8
@god-8 2 года назад
What solvent u using?
@unlockeduk
@unlockeduk 2 года назад
@@god-8use isopropyl alcohol and add acetone to reduce solubility once its disolved with minimal isopropyl :-)
@bibson1405
@bibson1405 2 года назад
Hexane or heptane
@tristantorus9026
@tristantorus9026 10 месяцев назад
How about naptha or denatured ethanol ?
@ولاءمصطفى-ط1و
@ولاءمصطفى-ط1و 2 года назад
Thanks, sir 🌹
@0166ชัยพรเทศะนันท์
อธิบายเกี่ยวกับเรื่องการกรอง
@nunyabisnass1141
@nunyabisnass1141 11 месяцев назад
Filtering is a physical separation of products. At the point where you are ready to filter,, you have rendered either the intended product or the impurity as a solid that can be separated by a filter, screen, or some other physical process. This can also be just letting the solids settle to the bottom while pouring (decanting) the liquid.
@siveange127
@siveange127 4 года назад
thanks man this really helped!
@RTU-mw8ft
@RTU-mw8ft 4 года назад
hi @Professor Dave. I really need your help. I have no idea how to study maths for IIT/JEE. Please start a playlist for that too just like you are doing for Chemistry. Plzzz sir. I have subscribed to all your 4 channels. You are amazing!!!!!!!!!
@RTU-mw8ft
@RTU-mw8ft 4 года назад
hi @Professor Dave. I really need your help. I have no idea how to study maths for IIT/JEE. Please start a playlist for that too just like you are doing for Chemistry. Plzzz sir. I have subscribed to all your 4 channels. You are amazing!!!!!!!!!
@justinjohnson6175
@justinjohnson6175 2 года назад
This ain’t materials science wtf bruh
@ProfessorDaveExplains
@ProfessorDaveExplains 2 года назад
This is organic chemistry.
@marox3G
@marox3G 2 года назад
Greeting! Good video! Can I recrystallize potassium chlorate this way? Thank you
@nunyabisnass1141
@nunyabisnass1141 11 месяцев назад
Yes, if you have the appropriate solvent. Assuming you used a double displacement method to convert the appropriate salt to the available chlorate, the salt will have a higher solubility than the chlorate corresponding to temperature. Typically heating to 100°C and cooling to 0°C twice twice while discarding the liquid each time will result a very pure chlorate because the chloride salt is that much more soluble in water that chlorates are.
@fazafiizzul391
@fazafiizzul391 2 года назад
I'd like to ask you a question if the nickel sulfate crystal is dissolved with ethanol at a high temperature to remove the impurities. then how can we get the nickel sulfate crystal after that process?
@bibson1405
@bibson1405 2 года назад
Freeze precipitation
@jq6120
@jq6120 Год назад
i'm confused by one part of this. Let's say you dissolve a solution with 50% product and 50% impurity, and perform recrystalization. What is preventing the impurity and product both forming cyrstals when you cool it down? If it did, then how would you seperate the two types of crystals in your beaker?
@charuyadav4869
@charuyadav4869 Год назад
Impurities are highly soluble in solvent at room temperature so when recrystallization occurs they remain dissolved in solvent.
@sirawesomeness7543
@sirawesomeness7543 Год назад
It only works if the impurities and product have very different properties. The impurity has to remain dissolved at the cooling temp (check its solubility) and the product has to have a way low solubility at that temp. Take sugar and baking soda for example. Baking soda has low solubility compared to sugar. You can dissolve them both, but if there’s less than 2 grams of sugar per mL of water, it will remain in solution at room temp. Meanwhile, the baking soda will crystallize out of solution until the concentration hits 0.1 grams per mL of water. Of course, solubility increases with each solute added so keep that in mind and expect lower yields for bulk impurities. Now take salt and baking soda for example. Their solubility is 0.35 g and 0.1 g per mL water respectively. You’d have to dilute between 0.1 and 0.35 g/mL to keep salt dissolved and baking soda hyper saturated. However, you’ll never be able to get more than 0.25 g of baking soda out per mL of water. And the closer to 0.35 g/mL you go, the more you risk getting salt in the mix. At the maximum scale, you’d only be able to get (1 - 0.1/0.35 *100)% or ~65% of your product (baking soda) out of solution. Whereas in the first example, you’d have (1 - 0.1/2 *100)% or ~95% of your product recovered
@nunyabisnass1141
@nunyabisnass1141 11 месяцев назад
The crystals have a higher affinity toward themselves, meaning they push out impurities into the solution. Let's say that hypothetically you as you said have two solvates with exactly the same solubility properties in that solvent. The two crystals would grow apart from one another, but likely still be interlaced making separation by this method difficult. You would get grains of both products inside of one another and would have to find an alternative method. Thankfully no two chemicals have exactly the same properties and separation is still possible, even if it's a huge pain in the ass.
@halaashraf2409
@halaashraf2409 3 года назад
Hello Professor I want to ask What is the recovery rate for benzoic acid when using 2.1 grams? please reply
@halaashraf2409
@halaashraf2409 3 года назад
What is the recovery rate of 2.1 grams of benzoic acid? please reply
@loldenmemes4615
@loldenmemes4615 3 года назад
@@halaashraf2409 the recovery rate is approximately 2.754 weeks, one day after the blue moon, roughly 32 seconds before lunch time
@fakhrulnawawi9681
@fakhrulnawawi9681 4 года назад
If I recrystalize using solvent that dissolve my compound at room temperature, does it mean my crystal cannot get back after I recool at 0 degree celcius?
@ProfessorDaveExplains
@ProfessorDaveExplains 4 года назад
hmm, well it might, it just depends on the precise melting point, but it's not the ideal situation
@babarazamsucks
@babarazamsucks 4 года назад
First!
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