SN1 Reaction Mechanism 

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Hi, at 8:10. From step 2 to step 3, the Energy Profile Diagram has shown decrease (endothermic) but during the 3rd step, when OH2+ changes to OH, it becomes more stable and energy is released. So it must be exothermic and the graph must increase at the third transition state.

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I think at 21:49 there's a mistake, because the ability of a compound to give SN1 reaction is measured by the stability of the carbocation that's going to be formed IMMEDIATELY after the removal of the old nucleophile as that is the rate determining step and the rearrangement shouldn't be considered in this case, hence the third compund will show most reactivity to SN1 as the carbocation that's going to be formed will have 5 alpha hydrogens for hyperconjugation stabilization

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24:40 Could easier way to find the better leaving group be finding the more stable base/more acidic leaving group?

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14:11 most reactive to sn1 23:05 best substrate for sn1 and sn2 24:40 aryl halides and benzyl halides do NOT work for sn1 25:11 to 26:01 iodide is a better leaving group than bromide as it can stabilize the -ve charge better. larger ions can stabilize a -ve charge better than smaller ions.

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24:21 They dont work so we are just supposed to remember this arbitrary rule? No explanation? WOW great lessons here! just remember this random rule !

at 4:05 wouldn't that carbon be a chiral center ?therefore producing a racemic mixture. anyone please chime in

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9:10 why did it just grow a random leg and H ?????

12:54

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