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Grignard Reagent Reaction Mechanism 

The Organic Chemistry Tutor
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This organic chemistry video tutorial discusses how to use the grignard reagent to reduce ketones and aldehydes into secondary and tertiary alcohols. It also explains how to reduce esters and acid chlorides to alcohols using the grignard reagent.
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3 май 2018

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Комментарии : 198   
@TheOrganicChemistryTutor
@TheOrganicChemistryTutor 6 месяцев назад
Final Exams and Video Playlists: www.video-tutor.net/
@user-zq4pw7yr4i
@user-zq4pw7yr4i Месяц назад
tnx
@vedavalliv9597
@vedavalliv9597 4 года назад
The word "thank you" is not enough for your efforts! It helps us a lot! Love from Tamilnadu,India❣
@thangam5006
@thangam5006 4 года назад
Sis I'm also from Tamilnadu
@vedavalliv9597
@vedavalliv9597 4 года назад
@@thangam5006 🙌
@ganeshsriram4941
@ganeshsriram4941 4 года назад
You are right, This video is helpful... And I'm also from Tamilnadu...
@vedavalliv9597
@vedavalliv9597 4 года назад
@@ganeshsriram4941 :)
@AnkitJosh
@AnkitJosh 4 года назад
I'm not from Tamil Nadu but I'm from India
@donaldmusenje5120
@donaldmusenje5120 3 года назад
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@donaldmusenje5120
@donaldmusenje5120 3 года назад
From zambia
@KawaiiBabyTragon
@KawaiiBabyTragon 6 лет назад
I needed this so bad last semester, thanks for making it now anyway.
@cedricchurch3632
@cedricchurch3632 5 лет назад
This video jusy came in really clutch for my 1st orgo 2 exam. Really preciate ypur vidoes they helped me through physics too
@meya4307
@meya4307 3 года назад
So basically, since feb. 2020, you've been my instructor. And THANK YOU SO MUCH.
@rohanbhide4495
@rohanbhide4495 2 года назад
thankyou for this video! You have selected the best questions and the right amount of questions for this topic! I really appreciate it!
@cunningclown7422
@cunningclown7422 3 года назад
Thanks! Cleared my concept very well! Great explanation!
@rohanbansal2324
@rohanbansal2324 5 лет назад
excellent video my man. keep up the great work
@criskris007
@criskris007 6 лет назад
Thank you for all your videos, I passed both organic chemistry courses with good grades because of you
@theobanai
@theobanai 4 года назад
Teacher nehi padhate the kya😕
@sounad3736
@sounad3736 2 года назад
@@theobanai tujhe teacher nehi padhate? Tu yaha kya kar raha hae ghochu?
@depharmily2064
@depharmily2064 4 года назад
you are the reason i do well in my exams and tests
@tomatrix7525
@tomatrix7525 4 года назад
Thanks man these are really great to watch
@Shred427
@Shred427 Год назад
This vidéos are so well explained, and help a lot to understand more easily the dark side of organic chemestry, so i need to say : Big thanks!
@chemchristv
@chemchristv Год назад
You are the best.... I want to be like you... Since my year 1 I have been using year video... Now I am a chemistry Tutor I am still watching your videos.. for proper explanation.. Thanks alot
@brianshang1069
@brianshang1069 6 лет назад
Awesome vid, can't say it enough.I smacked that sub button
@neilmashalkar5203
@neilmashalkar5203 4 года назад
great video! just some advice- keep the picture of the final product up for a few seconds longer- i can’t pause the video fast enough to see the product alone
@237BrillantBABOKA
@237BrillantBABOKA 2 года назад
Cette vidéo m'a rendu moins bête 😀, merci beaucoup Monsieur.L'anglais est vraiment très important pour la poursuite des études supérieures, dommage pour moi car je ne comprends pas...( BABOKA, DEPUIS LE CAMEROUN)
@guiaf_
@guiaf_ 3 года назад
Hope you're making millions by now my dude
@walterblack91
@walterblack91 3 года назад
hope he does....he deserves it totally
@gemlovergirl
@gemlovergirl 5 лет назад
You are the best tutor!!!
@dianed4938
@dianed4938 Месяц назад
you made me fall in love with chemistry through your videos
@ramisamaliath8658
@ramisamaliath8658 5 лет назад
Omg Thank you!!! This helped a lot
@Megan-je2lr
@Megan-je2lr 3 года назад
you deserve an award of some kind. you are the reason I'm passing my final in 2 hours :)
@mr.madguy6125
@mr.madguy6125 2 года назад
😂
@Frame381
@Frame381 6 лет назад
You are a saving grace! Thank you so much
@manishjat6263
@manishjat6263 5 лет назад
nice bhai
@MoeZokari
@MoeZokari 6 лет назад
Thank you sir... you are a life saver... wallah
@xxxdarksaskeexxxthesighing9575
@xxxdarksaskeexxxthesighing9575 3 года назад
Thank you for your vidéos. You cannot know how much you help me
@ujjwalkumarsingh5216
@ujjwalkumarsingh5216 5 лет назад
Thanku sir ..I had confusion in this part
@Naomicool100
@Naomicool100 4 года назад
A big „thank you“ from Germany 😇👌🏽
@surafeltesfu9953
@surafeltesfu9953 Месяц назад
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@raphaelkirangole4031
@raphaelkirangole4031 2 года назад
Thank you for your video 🙏🏽 it is really helping me following from Kenya
@JiyonKim5
@JiyonKim5 3 года назад
first time i feel like im understanding ochem!!! thank u so much! :)
@latte3728
@latte3728 4 года назад
Thank you for your help!
@duaamohamed5480
@duaamohamed5480 4 года назад
Am so proud of you
@nanditasanghvi
@nanditasanghvi 2 года назад
thaank you so so much you are brilliant and your teaching style is amazing
@shashaniou4
@shashaniou4 Год назад
thanks for your teaching!!
@valent9260
@valent9260 2 года назад
mann..... i wish could hire u privetely as my chemistry olympic mentor
@user-vj8vp3ti2t
@user-vj8vp3ti2t Год назад
thanks for all your videos
@jesusmrosario-claudio4104
@jesusmrosario-claudio4104 3 года назад
Thank you once again.
@ritankarmondal0411
@ritankarmondal0411 2 года назад
Can't thank you enough man! I was facing doubts in grignard reagent and this cleared everything! And a quick question. For the compound in 9:45 won't a ring expansion be more favourable before the addition of the -R group?
@ashaydwivedi420
@ashaydwivedi420 Год назад
this is an SNAE mechanism! rearrangement is only possible when a carbocation is formed. this reaction involves carbanion nucleophile and no carbocations are formed, so no rearrangements
@Ak-ix2xp
@Ak-ix2xp Год назад
You're such a gem
@Lolstarwar
@Lolstarwar 2 года назад
Helped me a lot thanks
@aakashpatel9650
@aakashpatel9650 9 месяцев назад
Great session
@aarongurung786
@aarongurung786 Год назад
My man's carrying my entire organic department staff
@hasanaliameal4298
@hasanaliameal4298 4 года назад
Thank you very much I am from Iraq and you help me by this lessons
@ivertylungu7834
@ivertylungu7834 11 месяцев назад
We really appreciate for your help
@patrycjapajdak2491
@patrycjapajdak2491 6 месяцев назад
A very useful video, thanks!
@ruq3tuieiotiyiiabyiuoyoppa413
@ruq3tuieiotiyiiabyiuoyoppa413 5 лет назад
thank you sir☺
@cringespot2928
@cringespot2928 Год назад
Thanks from Tamilnadu India 😍😀
@samajhdar3853
@samajhdar3853 9 месяцев назад
Thankyou , your deep explanation is attached to show more than one video and you are show everything in rxn ,what I to do. India (Hindi)
@svenvandeweerd7467
@svenvandeweerd7467 10 месяцев назад
great explanation!!!!
@DevilMode-pd8el
@DevilMode-pd8el Год назад
Thank you so much sir 💖from TN(India)
@kushagra5633
@kushagra5633 5 месяцев назад
Best explanation ❤
@zincion1
@zincion1 Год назад
Great video!
@darkphoenix6742
@darkphoenix6742 2 года назад
Very efficient!
@emmaaustin544
@emmaaustin544 3 года назад
Awesome! Thank you
@haryanwar1263
@haryanwar1263 5 лет назад
This better than my teacher
@An_ony_mous
@An_ony_mous 10 месяцев назад
Thanks alot. Now wherever I see RMgX I won't make mistakes.
@manjunatha15madhu36
@manjunatha15madhu36 5 лет назад
This videos is more usfull to us thank you
@ashokkumarsharma5666
@ashokkumarsharma5666 3 месяца назад
Surely a nice video with good explanation and high order jee leve questions
@Ihatwpwrsona5
@Ihatwpwrsona5 Месяц назад
wdym
@bailassandijani3788
@bailassandijani3788 3 года назад
could you please make a discussion about Reaction of Grignard Reagents with Epoxides thank you
@joshuaschamach4684
@joshuaschamach4684 3 года назад
Highest grade on my O Chem 1 final. High A in the class. Gracias.
@samarthgoswami5289
@samarthgoswami5289 6 месяцев назад
Thank you kind sir!
@gautalawrencebusa7474
@gautalawrencebusa7474 5 лет назад
Thank you very much.. This is what I need now
@nevabeenhxted2159
@nevabeenhxted2159 5 лет назад
Denhxv82 5 run to take 8 hours and turn
@mahdafikia529
@mahdafikia529 3 месяца назад
Thank you!!
@negar21100
@negar21100 2 года назад
@7:03 Why didn't O get protonated at this moment? Why did it kick the OCH3 out instead?
@single-cellshark6013
@single-cellshark6013 2 года назад
Badass. This guy is badass
@toxicevolution5940
@toxicevolution5940 3 года назад
Doesnt it matter that you change the position of the CH3 Group in the first example?
@alderamin1402
@alderamin1402 2 года назад
THANK YOU SIR
@CR1257
@CR1257 4 года назад
How do you know what side to put your reagent on? I keep thinking that you could choose either or because you’ll still end up with the same answer..? 08:26 I’ve seen others put their reagents on the aldehyde side and they’ve gotten it the answer right.
@laurensadowski2403
@laurensadowski2403 3 года назад
9:28 are there supposed to be that many carbons attached to the grignard reagent?
@ericraululyeetusdelyeetus5028
@ericraululyeetusdelyeetus5028 6 месяцев назад
Had to go to this video after seeing a legendary meme about the reagent. Who would've guessed a well edited clip of black'n'white daffy duck would be so funny?
@harshbalhara4389
@harshbalhara4389 2 года назад
Thanks sir !!!! Great love from INDIA. You really help me often!!
@fredt8167
@fredt8167 4 года назад
At 3:35, if we had to name this structure would be it be (A) 1-ethyl cyclohexanol or (B) 1-ethyl cyclopentanol? If its (B), why? when counting the longest chain starting with the ethyl group
@fourtyfourrr
@fourtyfourrr 8 месяцев назад
thank you so much
@magnesiumswift
@magnesiumswift 5 месяцев назад
really nice
@naomimascarenhas815
@naomimascarenhas815 4 года назад
THANK U
@gill.guntas
@gill.guntas 3 года назад
Very good
@footy1236
@footy1236 4 месяца назад
Thank you
@fantasiaford1283
@fantasiaford1283 Год назад
So, the Ch3Ch2, we use it twice because we need the oxygen to be negative in order for it to do the proton transfer of hydronium? So it can be an alcohol?
@senorbacon304
@senorbacon304 3 года назад
thank you so fucking much
@GoogleAccount-mz6vn
@GoogleAccount-mz6vn 4 года назад
At 7:14 why didn't the O¯ get protonated and turned into an alcohol instead?
@LA-cm9uo
@LA-cm9uo 4 года назад
You are an angel
@Fifi00416
@Fifi00416 4 года назад
thank you sooooooooo muchhhhhhhhhh
@juststudy9989
@juststudy9989 2 года назад
Hey dude u are OP
@urvitiwari6754
@urvitiwari6754 2 года назад
is attack by GR always SN2? is there a possibility of rearrangement or ring expansion?
@Code_eat_sleep
@Code_eat_sleep 3 года назад
Thanks a lot ...
@shihab5689
@shihab5689 2 года назад
Love from Bangladesh 😘.
@billalzerouali4472
@billalzerouali4472 2 года назад
Why is at times the h30+ is written under the arrow and other times it isnt even though its still used
@amirfilabs7716
@amirfilabs7716 9 месяцев назад
At 12:18 I believe this is an epoxide ring opening under basic conditions so the OH lands on the more substituted atom, please correct me if I’m wrong
@a0927020973
@a0927020973 2 года назад
4:28 Why magnesium will insert the carbon atom?
@sukrutha8788
@sukrutha8788 Год назад
thank you so much for this video! your explanation made everything easy to understand
@mikedavis7636
@mikedavis7636 3 года назад
What if you created a grignard reagent with bromobenzene and magnesium, then bubbled carbon monoxide through the solution?
@RotationMan13
@RotationMan13 5 лет назад
How do you know of the Carbon is partially positive or negative?
@ujjwalkumarsingh5216
@ujjwalkumarsingh5216 5 лет назад
When carbon is attached to a more electronegative atom like O of N ..the more electronegative atom attracts the shared pair of electrons from the electron cloud towards itself ..so it develops partial negative charge.
@nabiniim
@nabiniim 4 года назад
What I really want to know though is what happens to the Mg2+ and the Br- and also the H2O? 🤔😩
@robochibi
@robochibi 3 года назад
The MgBr is actually attached to the O- that was broken but it is not shown in the video. When an acid or hydronium is added than this attacks the MgBr bond and replaces it with a hydrogen thus giving an OH group. Your byproduct would then be a OHMgBr or ClMgBr depending on what you used to remove that MgBr group from the O- group.
@sandhyachaudhury956
@sandhyachaudhury956 4 года назад
Wow! That's all I can say! Wow!
@trentkirkwood4488
@trentkirkwood4488 2 года назад
Im learning from these this one just seemed like you were going kind of fast.
@yashkalia2311
@yashkalia2311 2 года назад
Thanks
@madeleineguzman5025
@madeleineguzman5025 8 месяцев назад
where did we get the 2 carbons to add to the 4 carbon chain on the last problem?
@rsinha4306
@rsinha4306 4 года назад
⭐awesome
@shammah5976
@shammah5976 4 года назад
example 4 at 7:34 why are there 2 ch2ch3 to react with??
@antique_key
@antique_key 2 года назад
Best 👌
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